Nano-Silica phosphoric acid: an efficient catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1H)-ones (thiones) under solvent-free or sonication conditions
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چکیده مقاله:
Two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1H)-ones (thiones) using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.
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ورودمنابع مشابه
nano-silica phosphoric acid: an efficient catalyst for one-pot synthesis of 3,4-dihydropyrimidin-2(1h)-ones (thiones) under solvent-free or sonication conditions
two simple protocols for the synthesis of three-component condensation reaction of an aldehyde, β-ketoester and urea or thiourea to obtain the 3, 4-dihydropyrimidin-2(1h)-ones (thiones) using nano silica phosphoric acid are reported. short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.
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Two simple protocols for the synthesis of tetrahydrobenzo[a]xanthenes-11-ones using nano silica phosphoric acid are reported. Short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.
متن کاملnano-silica phosphoric acid: an efficient catalyst for one-pot synthesis of tetrahydrobenzo[a]xanthenes-11-one under solvent- free or sonication conditions
two simple protocols for the synthesis of tetrahydrobenzo[a]xanthenes-11-ones using nano silica phosphoric acid are reported. short reaction times, high yields, reusability of catalyst and easy workup are some advantages of these protocols.
متن کامل4-Sulfobenzoic Acid as an Efficient Catalyst for the Preparation of 3,4-dihydropyrimidin-2-(1H)-ones Under Solvent-free Conditions
In this research, one-pot three-component synthesis of 3,4-dihydropyrimidin-2-(1H)-ones havebeen developed using Biginelli reaction from the interaction between ethyl/methyl acetoacetate,aromatic aldehydes, and urea/thiourea in the presence of 4-sulfobenzoic acid as a new, effective,inexpensive, and available bronsted acid. Avoidance of toxic and dangerous solvents, easy isola...
متن کاملNano Silica Phosphoric Acid: An Efficient Catalyst for the One- Pot Synthesis of 1, 2, 4, 5-Tetrasubstituted Imidazoles
Two simple protocols for the synthesis of 1, 2, 4, 5- tetrasubstitutedimidazoles using nano-SPA as a reusable, eco- friendly, inexpensive, and efficient catalyst are reported. Short reaction times, high yields, scale-up and easy workup are the advantages of these protocols.
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عنوان ژورنال
دوره 2 شماره 1
صفحات 17- 21
تاریخ انتشار 2012-01-01
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